@article {616,
	title = {Global methane emission through mud volcanoes and its past and present impact on the Earth{\textquoteright}s climate-a comment},
	journal = {International Journal of Earth Sciences},
	volume = {94},
	year = {2005},
	note = {940vyTimes Cited:11Cited References Count:15},
	month = {Jul},
	pages = {490-492},
	issn = {1437-3254},
	doi = {10.1007/s00531-005-0480-5},
	author = {Milkov, A. V. and Etiope, G.}
}
@article {564,
	title = {Molecular and stable isotope compositions of natural gas hydrates: A revised global dataset and basic interpretations in the context of geological settings},
	journal = {Organic Geochemistry},
	volume = {36},
	year = {2005},
	note = {929dvTimes Cited:101Cited References Count:138},
	pages = {681-702},
	abstract = {A global dataset of molecular and stable isotope compositions of gases released from 209 different specimens of natural gas hydrate is presented and discussed. The 26 hydrate-bearing areas from 21 geographic regions are grouped into high gas flux (HGF) settings, low gas flux (LGF) settings and hydrated gas accumulations (HGA). Methane (CH4) is the most abundant hydrate-bound gas, while CO2 and C2+ hydrocarbon gases are frequently present in small amounts. Non-hydrocarbon gases, such as H2S, are uncommon. The stable isotope composition of hydrate-bound gases varies significantly (e.g., delta(13)C of CH4 from -74.7 to -39.60 parts per thousand), suggesting that gases of both microbial and thermogenic origin form gas hydrates. Hydrate-bound gases are derived from autochthonous [Located predominantly within the gas hydrate stability zone (GHSZ)] and allochthonous (located in deep sediments) sources. The occurrence and concentration of gas hydrates in sediments are controlled not by the origin of gases, but rather by their sources, which in turn strongly depend on geological setting. Allochthonous gases (microbial and/or thermogenic) dominate in HGF and HGA settings where they are focused in the shallow GHSZ along faults, within mud volcanoes, in permeable carrier beds and other geological features from underlying petroleum systems. Relatively high concentrations of gas hydrate (average 5-15\% of pores and locally up to 100 parts per thousand of volume) occurring over small areas are typical of HGF and HGA settings. In contrast, autochthonous and diffuse allochthonous gases (mostly microbial) occur in stratigraphically and structurally simple LGF settings and result in relatively low concentrations of gas hydrate (average similar to 2\% of pores in the GHSZ) spread over large areas. The major implication of this finding is that successful prediction of resource and geohazard potential of gas hydrates is possible only if regional petroleum systems extending well below the GHSZ are properly evaluated. In addition to the diagnosis of origins and sources of hydrate-bound gases, molecular and isotopic data help to better identify hydrate-bearing intervals and provide valuable insights into the dynamics of hydrate-bearing sites. (C) 2005 Elsevier Ltd. All rights reserved.},
	issn = {0146-6380},
	doi = {10.1016/j.orggeochem.2005.01.010},
	author = {Milkov, A. V.}
}
